,成果详细信息-凯发网

您当前所在位置: 凯发网-凯发k8国际首页 > 学者

杨玉良

  • 125浏览

  • 0点赞

  • 0收藏

  • 0分享

  • 200下载

  • 0评论

  • 引用

期刊论文

the morphology and dynamics of the viscoelastic microphase separation of diblock copolymers

, , , , ,

macromolecules 2003, 36, 5383-5391,-0001,():

url:

摘要/描述

in this paper, the kinetics and morphology of viscoelastic microphase separation of diblock copolymers are investigated in detail. it is found that for a symmetric system (f=0.5), taking into account the bulk modulus differences between the two blocks, the classical randomly oriented lamellar morphology is not observed. instead, we find that droplets of the lower bulk modulus soft block disperse in a matrix of higher bulk modulus hard block. in the case of off-critical system (f=0.4), since an inherent composition asymmetry exists between the two blocks, the viscoelastic microphase separated morphology is also different from that normally observed, whether there is an apparent difference in the bulk moduli between two blocks. however, when a bulk modulus difference exists between the two blocks, the morphology is further altered. addition of random thermal noise to both the critical (f=0.5=and the off-critical system (f=0.4=weakens the suppression of concentration fluctuations, but no fundamental structural transformation is caused by the noise. since the abnormal morphology is observed on slow approach to the equilibrium state, we conclude that the viscoelastic effect may be largely responsible for the observed deviations between the experimentally measured and the mean-field theoretically calculated phase diagrams.

关键词:
  • 问答

    暂无问题,成为第一个提问者

【免责声明】以下全部内容由[杨玉良]上传于[2005年03月11日 01时03分44秒],凯发k8国际首页的版权归原创者所有。本文仅代表作者本人观点,与本网站无关。本网站对文中陈述、观点判断保持中立,不对所包含内容的准确性、可靠性或完整性提供任何明示或暗示的保证。请读者仅作参考,并请自行承担全部责任。

我要评论

全部评论 0

本学者其他成果

同领域成果

网站地图